TRUMPF Inc. to Introduce Entry Level Automated Laser Welding Machine at FABTECH 2022

TRUMPF to introduce new solution for entry level automated laser welding

FARMINGTON, Conn., September 12, 2022 – At FABTECH 2022, booth B6309, TRUMPF will unveil a new solution to help sheet metal fabricators get started in automated laser welding. Fabricators no longer must choose between costly and time-consuming manual welding or large,  automated systems that are expensive and complicated to operate. Enter the TruLaser Weld 1000, an entry level solution from TRUMPF which offers smaller companies the benefits of automated laser welding, boosting the productivity of their production processes to provide a real
competitive edge. The new system is particularly suitable for job shops that weld products such as electrical cabinets, sheet metal boxes and covers.

 

Simple to program

The TruLaser Weld 1000 makes programming quick and easy. Unlike most commercial systems that require several days of training, the information needed to run the TruLaser Weld 1000 can be obtained through e-learning. The system incorporates a robot whose operation is based on the concept of a collaborative robot, or cobot. However, its six-axis articulated arm enables it to move much faster and more precisely than a standard cobot, resulting in higher-quality weld seams and less non-productive time. The operator manually guides the robot over the seams on the part to be welded and presses a button to mark the relevant waypoints. Then, the software creates the weld program. “Depending on the part, this style of programming – where you simply guide the robot along the seam – takes a matter of minutes. So, it’s also a good choice for
small-batch production,” says Masoud Harooni, head of the welding technology product group at the TRUMPF Inc. Smart Factory. With a compact format and dimensions of 17 by 7 by 9 feet, the system fits most manufacturing facilities and can typically be installed and commissioned within a single day.

 

Double the work area at the touch of a button

Efficiency is a key advantage of the TruLaser Weld 1000. The work area is divided into two sections with a partition. While the robot welds a part on one side of the partition, the operator can load and unload on the other. Once the welding process is finished, the robot automatically switches to the other side along a linear axis and starts work on the next part. This design saves time and boosts productivity. If the operator wants to weld larger parts, the partition can be raised automatically to provide a work area that is double the size. To maximize safety, TRUMPF
developers installed a wall behind the robot to ensure that no laser light can escape during welding. This keeps employees safe when they are working right next to the robot.

 

High-quality welding of thin sheets

TRUMPF uses a 3kW solid-state laser as the system’s beam source. The high-power laser energy rapidly penetrates the sheet when and where it is needed, making it easier to weld thinner sheets without distortion. In most cases, no post-processing is required, so companies can save time and cut costs. The TRUMPF laser system is also a great choice for processing thicker sheets.

 

 

TruLaser Weld 1000

A new entry level solution from TRUMPF, the TruLaser Weld 1000 offers smaller companies the benefits of automated laser welding. The TruLaser Weld 1000 creates a competitive edge by boosting productivity and is particularly well-suited for job shops that weld products such as electrical cabinets, sheet metal boxes and covers.

 

About TRUMPF
TRUMPF is a high-tech company offering manufacturing solutions in the fields of machine tools and laser technology. The company drives digital connectivity in the manufacturing through consulting, platform products and software. TRUMPF is a technology and market leader in highly versatile machine tools for sheet metal processing and in the field of industrial lasers. In 2020/21, the company employed 15,000 people and generated sales of about $4.2 billion. With over 80 subsidiaries, the TRUMPF Group is represented in nearly every European country as well as in North America, South America and Asia. The company has production facilities in Germany, France, the United Kingdom, Italy, Austria, Switzerland, Poland, the Czech Republic, the United States, Mexico and China. Find out more about TRUMPF at www.trumpf.com

TRUMPF Inc. Exhibits Welding and Marking Technology, and Additive Manufacturing at IMTS 2022

TRUMPF to exhibit automated arc welding, 3D laser welding, 3D laser marking, and additive manufacturing technology

FARMINGTON, Conn., July 6, 2022 – TRUMPF will show the latest in automated arc welding, 3D laser welding, 3D laser marking, and additive manufacturing technology at the 2022 IMTS show taking place September 12 to 17 at the McCormick Place in Chicago, Illinois. In booth 236217, TRUMPF will highlight the TruArc Weld 1000, an automated arc welding system designed for easy and affordable high-mix, low-volume production. The booth will also showcase laser technology for 3D processing, including the TruLaser Station 7000 fiber, a versatile, compact and fully-equipped low-investment 3D laser welding system, and a TruMarkStation 7000 with a TruMark 6030 marking laser for high-performance 3D laser marking.

TRUMPF will highlight laser 3D printing technology at a second exhibit in the Additive Manufacturing pavilion. In booth 433037, TRUMPF will feature the TruPrint Green Edition, a highly productive metal additive manufacturing laser machine designed for specialized applications, including the 3D printing of copper, copper alloys, gold and other precious metals. TRUMPF’s Additive Manufacturing (AM) booth will also a virtual showroom for participants to take a deep dive into the variety of laser technology and AM applications offered by TRUMPF and to help determine the right equipment for different application and part requirements.

TruArc Weld 1000: Automated arc welding


The TruArc Weld 1000, TRUMPF’s automated arc welding system, makes it easy for fabricators to get started in automated welding. For affordable high-mix, low-volume production, the TruArc Weld 1000 is the perfect solution. A collaborative robot, or “cobot,” makes it easy to program and weld in just minutes. Even first-time operators can program by simply guiding the cobot by hand. Programming is greatly simplified by the operating unit on the welding torch and factory settings for different materials and sheet thicknesses. Thanks to the rapid programming, fabricators have a cost-effective means of tackling short production and single-part runs. Overall, the TruArc Weld 1000 creates a process that is more efficient than manual welding and produces a high-quality weld seam.

TruLaser Station 7000 fiber: Cost-effective and versatile 3D laser welding



The TruLaser Station 7000 is a versatile, compact, and fully equipped low-investment 3D laser welding system. The higher power laser enables a broad range of applications. The TruLaser Station 7000 facilitates efficient and ergonomic 3D laser welding of small assemblies, such as sensors, rotationally symmetrical components, and medical devices. The large work area also makes it possible to integrate fixtures and process larger components in a small installation area. Fully integrated image processing ensures reliable weld seam positioning.

TruMarkStation 7000 with TruMark 6030: high-performance 3D laser marking


TRUMPF will demonstrate laser marking of 3D metal printed parts with a TruMark Station 7000 laser marking station that features a TruMark 6030 marking laser and VisionLine 3 feature recognition capability. The TruMark 6030 is a high-performance marking laser with 3D functionality. The laser’s outstanding beam quality and high power densities ensure clean material removal and high-contrast markings. The TruMark 6030 can be integrated into production systems quickly and easily.

TruPrint Green Edition: highly productive 3D printing of copper, copper alloys and precious metal


In the Additive Manufacturing pavilion, TRUMPF will show the TruPrint Green Edition, a highly productive metal additive manufacturing laser machine designed for specialized applications including the 3D printing of copper, copper alloys, gold and other precious metals. With a wavelength of 515 nm, the TruDisk 1020 green laser makes it possible to 3D print highly reflective materials such as copper, which can be extremely difficult or impossible to process with infrared wavelengths. The TruPrint Green Edition can also manufacture parts made of copper alloys such as CuCr1Zr with a larger process window and higher productivity than traditional infrared laser metal fusion laser systems. TRUMPF’s Additive Manufacturing (AM) booth #433037 will also feature a virtual showroom for participants to take a deep dive into the AM products offered by TRUMPF and help to determine the right equipment for different application and part requirements. In addition, TRUMPF will display parts that demonstrate their laser metal deposition (LMD) and laser metal fusion (LMF) applications for the aerospace, space, medical industries.

 

About TRUMPF

TRUMPF is a high-tech company offering manufacturing solutions in the fields of machine tools and laser technology. The company drives digital connectivity in the manufacturing through consulting, platform products and software. TRUMPF is a technology and market leader in highly versatile machine tools for sheet metal processing and in the field of industrial lasers. In 2020/21, the company employed 15,000 people and generated sales of about $4.2 billion. With over 80 subsidiaries, the TRUMPF Group is represented in nearly every European country as well as in North America, South America and Asia. The company has production facilities in Germany, France, the United Kingdom, Italy, Austria, Switzerland, Poland, the Czech Republic, the United States, Mexico and China. Find out more about TRUMPF at www.trumpf.com

 

Press contact:

Catherine Flynn, APR
Public Relations & Communications Specialist

860 255-6518

catherine.flynn@trumpf.com

TRUMPF Inc.

3 Johnson Ave. Farmington, CT 06032

TRUMPF to Showcase Latest Laser Technology Advancements & Products at Photonics West 2022

FARMINGTON, Conn., January 21, 2022 – In booth 327 at Photonics West 2022, TRUMPF Inc. will showcase its TruMicro 2000 Series, TruMicro 6000 Series, TruFiber P Compact, and TruMark Station 7000 laser marking station with a TruMark 6030 laser marking system and VisionLine 3 feature recognition capability. TRUMPF will also display two Tool Bars highlighting its wide range of laser technology offerings and VCSEL laser diode technologies as part of its exhibit at the Moscone Center in San Francisco, California.

New Glass Processing Optics for TruMicro Lasers

 

                       

 

The TruMicro 2000 series laser is equipped with two of the latest innovations in optics for beam formation when cutting and welding glass: TOP Cleave and TOP Weld. TOP Cleave optics enable quick laser cutting of glass parts with excellent edge quality and nearly eliminates necessary post processing. TOP Weld makes it possible to weld glass with a top layer as thick as 8mm and also weld both glass to glass and glass to metal. TOP Weld can create a tight, hermetic seal to keep liquids and gases in or out. Both optics work with the fiber-based ultrashort pulse lasers in the TruMicro Series 2000, distinguished by its compact and light design. TruMicro Series 2000 solid-state lasers are tailored for precision micro-processing with an optimal combination of quality, productivity, and profitability.

The TruMicro 6330 ultrafast industrial laser also cuts glass and can separate flexible printed circuit boards. Designed for batch production in consumer electronics and other industries, the TruMicro 6330 is ideally suited for high-speed scanning applications such as cutting polymer stacks and processing OLED displays. Notable for strong performance, stability and quality, the ultrashort pulse lasers of the TruMicro Series 6000 generate laser pulses that can be linearly amplified to very high pulse energies.

TruFiber 200 P Compact

One of TRUMPF’s compact, fiber-based solid-state lasers, the TruFiber 200 P Compact will also be shown. This robust fiber laser resonator has a compact footprint, long service life, and patented technology that protects the laser from the damaging effects of back-reflected light, enabling it to process materials, such as copper, brass or gold, easily and productively. TruFiber P Compact lasers are suitable for a variety of applications including additive manufacturing and precision laser cutting and welding.

Laser Marking Station with TruMark 6030 and VisionLine 3

At the show, TRUMPF will be demonstrating a TruMark Station 7000 laser marking station featuring a TruMark 6030 laser marking system and VisionLine 3 feature recognition capability. The TruMark 6030 is a high-performance marking laser with 3D functionality. The laser’s outstanding beam quality and high power densities ensure clean material removal and high-contrast markings. The TruMark 6030 can be integrated quickly and easily into production systems and can reduce process time by up to 25 percent through its available high average power and pulse energy at the workpiece. The VisionLine 3 camera-based image processing product creates an additional level of safety during processing. VisionLine 3 automatically detects component positions before welding and aligns each job accordingly.

Also on Display: VCSEL and Other Laser Technology

 

 

The booth will also showcase TRUMPF’s wide range of other laser technology offerings, including the VCSEL laser diode technologies of TRUMPF Photonic Components. TRUMPF Photonic Components is a global technology leader supplying state-of-the-art VCSEL and photodiode solutions for the consumer electronics, datacom, industrial sensing and heating markets. Experts anticipate this growing market will drive the future of mobile electronics, autonomous driving, optical data communication, and quantum technology.

TRUMPF will be located at booth 327 in the Moscone Center in San Francisco, California. Press kits will be available at the booth.

 

 

About TRUMPF

TRUMPF is a high-tech company offering manufacturing solutions in the fields of machine tools and laser technology. The Company drives digital connectivity in the manufacturing through consulting, platform products and software. TRUMPF is a technology and market leader in highly versatile machine tools for sheet metal processing and in the field of industrial lasers. In 2020/21, the company employed 15,000 people and generated sales of about 3.5 billion euros. With over 80 subsidiaries, the TRUMPF Group is represented in nearly every European country as well as in North America, South America and Asia. The company has production facilities in Germany, France, the United Kingdom, Italy, Austria, Switzerland, Poland, the Czech Republic, the United States, Mexico and China.

Find out more about TRUMPF at www.trumpf.com

Laser Additive Manufacturing’s Journey to Commercialization

By Andrew Albritton

As seen in LIA TODAY

LASER ADDITIVE MANUFACTURING CHALLENGES

Laser Additive Manufacturing (LAM), as it pertains to powder based manufacturing, is a technique that utilizes the interaction of lasers and base materials to construct a product, rather than removing material from a pre-constructed block of material. LAM is quickly approaching the critical point of being more than a method to produce prototypes and small runs of one-off parts – it is poised to turn everything we know about mass production on its head. Professor Dr. Minlin Zhong, President-Elect of LIA and Director of the Laser Materials Processing Research Center at Tsinghua University, believes it surpasses all available alternative methods.  Prof. Dr. Zhong  says “LAM shows obvious advantages on freeform manufacturing, including free geometry, free structures, free strengthening mechanism, free microstructures, free performance and even free scale (from macro, to meso, to micro, to nano),”. Manufacturers who use LAM are able to reduce the waste of materials commonly associated with traditional subtractive manufacturing methods; decrease the weight of parts by cutting out filler materials; and have more control over material properties resulting in stronger, more complex, lighter, and more efficient parts. With such exceptional technology currently at our disposal, why hasn’t LAM been more widely adopted?

IT’S EXPENSIVE

One of the most commonly cited reasons is that the costs to produce parts through LAM are prohibitive. The key driver of these high costs is that the supply chain for metal powders is not yet optimized for LAM technology. Materials are expensive, custom made, or not readily available. The Metal Powder Industries Federation (MPIF) states in its 2017 PM Industry Roadmap that, “A better understanding of the precursor materials impact on the metal AM process is required. Traditionally, precursor materials have been existing thermal spray powders that have not been refined/tuned to the AM process limiting optimization.” LAM parts producers are often using metal powders that have not been designed for use in LAM processes, which frequently results in suboptimal products.

According to MPIF, as of 2017, there are approximately 12 suppliers of metals for Additive Manufacturing (AM) for the international market, most produce stainless steel, cobalt-chrome, and titanium, with a few supplying aluminum alloys, copper, super alloys, platinum, Inconel, tungsten, molybdenum, and tool steels. With so few suppliers and a sparse number of common material types, there is a bottleneck for providing quality affordable metal powders to the LAM industry. With companies expanding the selection of materials that can be laser processed, it is vital that the problem of material availability be resolved. For example, Nuburu has produced a “blue” laser which operates at the 450 nm wavelength, and is capable of processing gold, aluminum, brass, and copper.

SUPPLY AND DEMAND

What can be done to improve the supply chain and reduce the cost of LAM part production? The metal powder industry does not supply enough quality powder to support widespread adoption of LAM, while early adopters of LAM applications do not create enough demand to drive competition into the metal powder market to reduce prices. A first step to get these industries operating in unison will be the creation and mass adoption of standards, specifications, and best practices in regards to metal powders. By standardizing metal powder properties for best final product properties, metal powder suppliers would be able to build up an inventory without relying on custom special orders. Specifications on how surplus powder from a project can be reused could also help introduce addition cost savings to manufacturers.

STANDARDS FOR QUALITY CONTROL

Another hurdle for LAM is microstructural quality, uniformity, and repeatability. To become a replacement for more legacy manufacturing methods, LAM needs to produce parts consistently and continuously that are to specifications. With traditional subtractive manufacturing methods, there are several quality control points where product is inspected and defects are addressed prior to the next step, resulting in no wasted effort past the point of failure. With LAM, the part in question is created from the ground up; this determines the final product’s quality, microstructure, and mechanical properties simultaneously. The process is completed with either a perfect or defective final product. Paul Denney, Director of Advanced Process Development with IPG Photonics, states, “Unlike machining where you start with a “block” of material with known quality and properties, additive production of parts requires a combination of motion with the prediction of the microstructures, mechanical properties, and stresses. Because the properties are closely connected to how the material is deposited, this greatly complicates the development of processing procedures and parameters.”

What methods can be implemented into a given LAM process to help ensure quality of the final product? The first quality control concerns are addressed long before the process begins. Starting materials must be certified as appropriate for the application, the order of operations of the production device should be scrutinized to ensure that the final product will be to spec with minimal waste, and the machine itself must be operating at peak parameters. As the production of a LAM product can take an extended amount of time, any loss of power to the point of interaction can have detrimental effects to the end product and even the products in queue. Loss of power can be caused by an actual power failure, a dirty or damaged optic, or other origins. With the structural integrity of a LAM part resting critically on the success of every step of the process, it is imperative that the process is stringently optimized and the machine is operating at peak performance. Here is what Paul Denney has to say about the subject:

“Because of the additive manufacturing approach in bed based systems, even if defects can be detected and possibly ‘corrected’, any changes may not be possible. An example of this may be what is done if a ‘defect’ is flagged in a single part in a batch of parts being produced. One approach would be to stop the processing and ‘correct’ the defect. However, if this is done then the thermal history for all of the parts may be altered and all parts may now be out of the desired properties. Another approach would be to stop processing on the part with the defect, but this again would alter the heat load on the complete batch or the time between other parts being produced which may again alter the properties. So any monitoring system will need to detect changes prior to the formation of any defects while at the same time any corrections must be made within the acceptable parameter range.”

There is a thin line between success and failure: one small interruption can ruin an entire batch of product. What can be done to prevent this?

As Paul explained, this is not a single issue, LAM processes need both a method to detect defects and the ability to immediately respond to them. A starting point is to ensure that redundancies are incorporated into the build process so that if a common defect occurs at a certain stage, there are defined responses the system can take automatically to correct them. In the case of a laser lens issue, it may be beneficial to incorporate additional laser delivery systems to the process as a redundancy to pick up where a suboptimal device has failed in real time.

EVALUATING THE FINAL PRODUCT

In addition to inline defect detection, the industry as a whole will require a standardized best practice for evaluating finalized parts. For traditional manufacturing methods, a sample of the produced part pool is selected for evaluation via destructive and non-destructive tests to certify whether a set of parts are built to specifications. As many LAM-produced parts are complex and costly to produce, it seems wasteful to destroy a set of them to certify them. In the paper “Evaluation of 3d-Printed Parts by Means of High-Performance Computer Tomography” presented at ICALEO 2017, authors Lopez, Felgueiras, Grunert, Brückner, Riede, Seidel, Marquardt, Leyens, and Beyer reviewed the viability of X-ray Computer Tomography (CT) and 3d scanning as methods to detect inferior AM parts. The paper concludes that the CT method best fits the needs of the AM industry. According to Lopez et. al, “Computer tomography can quantify all complex structures in scope of the proposed demonstrator and delivered deviation values of the measured structure, providing a good base for comparison across demonstrators made by different methods, materials and dimensions. Porosity or defects down to 3 µm can be determined by the used CT system.” Currently, CT scanning a LAM part is a time consuming process, but with additional focus on improvement it could become an essential quality non-destructive control method for finalized parts to evaluate complex internal structures.

TOO MANY ALTERNATIVES

A third barrier to the spread of LAM is the multitude of alternative methods in the industry. As stated by Prof. Dr. Zhong, “Some conventional metal deposition technologies such as arc building-up welding, plasma building-up welding and electronic building-up welding can also fabricate metallic components in near shape. Their deposition rate and productivity may be high and the costs may be lower, but normally they are limited in fabricating complex geometry and accuracy.” Freeform manufacturing is where LAM excels, but despite its many advantages over alternative methods, it has an Achilles heel.

One advantage of alternative manufacturing methods is the speed at which a product can be produced. However, according to Paul Denney, this speed gap is closing faster every day.

“While higher laser powers allow for higher deposition rates but at the expense of lower resolution, some researchers are looking to maintain the resolution by combining multiple lasers into an additive deposition system. Research groups and equipment builders are investigating how best to handle multiple lasers in the same processing area. There are other areas that may be investigated including power distribution to improve the interaction between the power and laser beam to improve efficiency of the process and to minimize defects. This could improve the deposition rates while at the same time maintaining quality.”

Prof. Dr. Zhong hopes that soon LAM researchers will, “improve the materials diversity, increase the dimension (to square meters), increase the deposition rate and decrease costs. A hybrid approach to combine LAM with the conventional additive manufacturing methods may be a solution to achieve the above targets.” The concept of a hybrid production system that can combine multiple lasers with fast alternative methods where complexity is not a requirement could lend itself to faster build times.

THE LATE ADOPTERS

Earlier in the article, we touched on the final barrier to the wide spread success of LAM: industry standards. Current standard offerings from ASTM and ISO cover Design, Materials and Processes, Terminology, and Test Methods. Additionally, new processes are created frequently and new standards are being developed every year in an attempt to keep up. It is unclear how much of the industry has adopted these existing specifications. Until the entire market accepts a set of standards for all steps of the Additive Manufacturing process and supply chain, the evaluation of AM parts will remain a costly endeavor that will limit AM’s potential. MPIF expresses a bleak outlook on metal AM in its State of the PM Industry in North America – 2017 document: “Despite all the fanfare, true commercial long-run production still revolves around only three product classes: titanium medical implants, cobalt-chrome dental copings, and cobalt-chrome aircraft nozzles.” The truth of the matter remains that without a set of clearly defined standards, the LAM industry will continue to remain confined to early adopters like the Aerospace and Medical fields. With the benefits in intricacy and weight saving advantages LAM should have obvious opportunities in the automotive and electronics industries.

Markets are watching LAM for innovative uses before taking the plunge and embracing the technology. Currently, LAM may appear to have a bad Return on Investment (ROI) if producers only hope to replicate their existing products through LAM rather than innovating their parts to capitalize on its strengths. In the words of Paul Denney, “If AM is supposed to make big impact, companies are going to have to rethink their parts; determine how AM allows for changes in the design and possibly improve the performance. The benefits can come in many forms which could be a weight savings, a production savings, and/or a performance savings.” The industry needs to challenge its way of thinking about production to allow the benefits inherent to LAM to propel their production and parts to new levels of performance. Paul Denney provided the following illustration: “With the formation of properties ‘locally’ instead of in ‘bulk,’ it is possible to produce ‘gradient’ materials. The ‘gradient’ can come by changes to the properties of a given chemistry of material or by using materials with different chemistries. As an example: a bracket could be produced for a jet engine that has high temperature properties near the engine but as the bracket extends to an attachment point, the properties/chemistry can be altered to improve the fatigue properties.”

LAM has a bright future and many engineers and scientists are working to unlock its full potential. Once the barriers of the supply chain, dynamic quality control, speed of production, and process standardization have been resolved, it is highly likely the LAM will be a manufacturing method of choice.

 

ACKNOWLEDGEMENTS

Paul Denney, Director of Advanced Process Development with IPG Photonics and LIA’s Past President

Prof. Dr. Minlin Zhong, Director of Laser Materials Processing Research Center at Tsinghua University

and LIA’s President-Elect

 

References:

Lopez, E., Felgueiras, T., Grunert, C., Brückner, F., Riede, M., Seidel, A., Marquardt, A., Leyens, C., Beyer, E. (2018). Evaluation of 3D-printed parts by means of high-performance computer tomography. Journal of Laser Applications 30, 032307; https://doi.org/10.2351/1.5040644

Inventors Synthesize Graphene with Lasers

As featured in the LIA TODAY

By Liliana Caldero

Graphene – it’s the two-dimensional (2D) allotrope of carbon atoms that ignited the imaginations of researchers across the globe. Heralded as a ‘miracle material’, its potential seemed limitless and it was predicted to usher in the next generation of technology. Flexible, stronger than steel, transparent, lightweight, and an amazing conductor of heat and electricity, it was going to revolutionize everything from household electronics to biomedical nanotechnology.

 

THE PROBLEM

Yet, nearly eight years after Dr. Andre Geim and Dr. Konstantin Novoselov earned the Nobel Prize in Physics for first isolating graphene and identifying its properties, graphene has encountered barriers to moving out of the lab and into the marketplace. According to Prof. Dr. Aravinda Kar of the University of Central Florida’s Center for Research and Education in Optics and Lasers (CREOL), one of the most prominent barriers has been finding scalable manufacturing processes that can produce graphene of a quality and quantity ready for consumers and businesses.

Graphene is notoriously difficult to synthesize in large quantities at a consistent quality. Early methods of isolating graphene involved a slow and tedious mechanical exfoliation technique; the researchers would extract a thin layer of graphite from a graphite crystal using regular adhesive tape, continually reducing the graphite sample by sticking the tape together and pulling it apart until only a small, 2D section of carbon atoms with a honeycomb lattice remained. Graphene’s unique characteristics are only present when it is one, two, or three layers of atoms thick – any thicker and it becomes graphite, losing all of the exceptional properties of graphene. The tape exfoliation method, although useful for the lab, was not going to translate very well to an industrialized process.

 

SOLVENT-AIDED EXFOLIATION AND CVD

Two of the more promising and potentially scalable methods of producing graphene are solvent-aided exfoliation and chemical vapor deposition (CVD). In solvent-aided exfoliation, sonication is used to exfoliate graphene crystals which are then further separated in a solvent and later gathered into graphene monolayers.  Scientists at the National University of Singapore have identified a flocculation method that reduces the amount of solvent needed for their exfoliation process, which could yield graphene using far less solvent than was previously needed. Another method experiencing innovation is CVD, which uses thermal chemical reactions to ‘grow’ graphene on substrates of specific materials, typically copper or silicon. Recently, engineers at MIT developed a CVD process for producing graphene filtration membrane sheets at 5 cm per minute. One of the biggest issues with traditional CVD and exfoliation methods is the need to transfer graphene from its fabrication platform to a substrate. Lasers are going to change that.

 

THE MISSING PIECE – LASERS

Lasers may provide yet another avenue to the elusive mass production of graphene, with an eye toward innovating the semiconductor industry. In 2003, Kar, along with Dr. Islam Salama and Dr. Nathaniel Quick, realized that laser direct writing could be used to fabricate carbon-rich nanoribbons on a silicon carbide (SiC) wafer in a nitrogen rich environment. Although these ribbons were too thick to be considered graphene, Kar believed that with a few changes, this process could be reworked to synthesize graphene in situ on a large scale, very quickly. In 2013, Kar and Quick were issued a patent for a Laser Chemical Vapor Deposition (LCVD) method that could be scaled for mass production.

Their method involved a few simple components: a frequency doubled Nd:YAG (green) laser of 532 nm wavelength, methane (CH4) gas, a silicon substrate, and a vacuum chamber.

The 532 nm wavelength corresponds to a photon of energy 2.33 eV, so the energy of two photons is 4.66 eV, just within the range of the C-H bond energy (4.3-4.85 eV) in CH4. Focusing the laser beam to a high intensity can induce two-photon absorption at the focal plane, causing the decomposition of CH4 to release the hydrogen atoms and deposit carbon atoms only on the substrate. The laser heating of the silicon substrate is just low enough to avoid melting the silicon, while providing sufficient thermal and electromagnetic energies to assist the carbon-carbon bonds rearrange into graphene’s trademark hexagonal pattern.

An experimental set-up for multiphoton photolytic laser chemical vapor deposition (LCVD) of graphene from methane precursor. Image courtesy of Dr. Kar and Dr. Quick.

LASER DIRECT WRITING OF GRAPHENE

Kar believes this process could be adapted to add graphene directly onto any substrate. Using laser direct writing, a company could easily draw graphene circuits onto a board. For companies using a hybrid approach, the graphene could be deposited at precise points as interconnects. “You would have all the CAD/CAM capability you could want,” says Quick. Currently, green lasers are available at high output powers, 100 W in continuous wave mode from most large laser manufacturers, so adding this additional step to the manufacturing pipeline for semiconductors would be easy and inexpensive compared to other methods.

At 1.9 cm per second, or 45 inches per minute, this method of graphene production is fast and efficient. This LCVD method offers control over the number of graphene layers, whether one, two, or three are required.  This process also removes the need to manually place graphene onto its intended location, as it is synthesized precisely where it should be. It’s also worth mentioning that this process is conducive to minimal environmental impact, as the unreacted methane and hydrogen byproducts can be captured to be recycled and reused.

 

A LOOK AT THE FUTURE

Picture this: a template is placed over a substrate and a line-shaped laser beam sweeps over it briefly or a beam of large cross-sectional area illuminates the entire template in one shot; when the template is removed, an intricate graphene design has been printed onto a circuit board. That is the future that Kar says is possible, with the right equipment. He suggests that we need manufacturers to develop lasers producing line-shaped beams or large area beams with spatially uniform intensity profile to realize this vision cost-effectively. He emphasizes that a true line-shaped beam produced by a slab laser system or an array of optical fiber laser would be necessary, as shaping the beam synthetically by changing the shape of an aperture would result in too much lost energy. With this technology, graphene could easily be printed onto circuit boards immediately, only where it’s needed, saving in material costs and time.

Nearly 14 years after the excitement first began, researchers are still exploring the potential uses of graphene; from applications in microsupercapacitors to Organic LEDs in flexible displays to ultra-sensitive optical sensors, and even lightweight body armor, the possibilities are still as exciting as ever.

 

Acknowledgements

Prof. Dr. Aravinda Kar, University of Central Florida, CREOL

Dr. Nathaniel Quick, Executive Director of LIA

 

LEARN MORE

Laser Formation of Graphene: United States Patent 8617669. (N. Quick, A. Kar)
http://www.freepatentsonline.com/8617669.html

NUS-led research team develops cost effective technique for mass production of high-quality graphenehttp://news.nus.edu.sg/press-releases/mass-production-graphene-slurry

MIT researchers develop scalable manufacturing process for graphene sheetshttps://newatlas.com/mit-manufacturing-graphene-filtration-membranes/54274/